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\(CH_3CN/MeOH/H_2SO_4\) (100/1/0.05, \(v/v/v\))
\(CH_3CN/MeOH/H_2SO_4\) (100/10/0.05, \(v/v/v\))
\(CH_3CN/MeOH/H_2SO_4\) (100/1/0.05, \(v/v/v\)), \(\%\) |
\(CH_3CN/MeOH/H_2SO_4\) (100/10/0.05, \(v/v/v\)), \(\%\) |
\(CH_3CN/MeOH/H_2SO_4\) (\(v/v\)) |
90 |
10 |
100/1.9/0.05 |
80 |
20 |
100/2.8/0.05 |
70 |
30 |
100/3.7/0.05 |
60 |
40 |
100/4.6/0.05 |
50 |
50 |
100/5.5/0.05 |
40 |
60 |
100/6.4/0.05 |
30 |
70 |
100/7.3/0.05 |
20 |
80 |
100/8.2/0.05 |
10 |
90 |
100/9.1/0.05 |
5.5 \(\%\) / 30 \(min\) = 0.18(3) \(\%/min\)
ID |
t, \(min\) |
\(PG\) |
06.544 |
\(PC\) |
20.820 |
\([CH_3CN/MeOH/H_2SO_4; 100/0.5/0.05, v/v/v]\)
\([CH_3CN/MeOH/H_2SO_4; 100/10/0.05, v/v/v]\)
\([CH_3CN/MeOH/H_2SO_4; 100/0.5/0.05, v/v/v], \%\) |
\([CH_3CN/MeOH/H_2SO_4; 100/10/0.05, v/v/v], \%\) |
\([CH_3CN/MeOH/H_2SO_4, v/v]\) |
90 |
10 |
100/1.45/0.05 |
80 |
20 |
100/2.40/0.05 |
70 |
30 |
100/3.35/0.05 |
60 |
40 |
100/4.30/0.05 |
50 |
50 |
100/5.25/0.05 |
40 |
60 |
100/6.20/0.05 |
30 |
70 |
100/7.15/0.05 |
20 |
80 |
100/8.10/0.05 |
10 |
90 |
100/9.05/0.05 |
5.25 \(\%\) / 30 \(min\) = 0,175 \(\%/min\)
0 \(min\): 100/0 \(\%\)
5 \(min\): 100/0 \(\%\)
30 \(min\): 50/50 \(\%\)
31 \(min\): 100/0 \(\%\)
Градиент 90/10 → 40/60 (см. изображения):
0 \(min\): 90/10 \(\%\)
30 \(min\): 40/60 \(\%\)
31 \(min\): 90/10 \(\%\)
40 \(min\): 90/10 \(\%\)
6.20 - 1.45 = 4.75 4.75 \(\%\) / 30 \(min\) = 0,158333333 \(\%/min\)
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